Two techniques: vapor pressure controlled Czochralski (pCZ) and vertical Bridgman.
pCZ in a pulling technique, the crystal being pulled up from the inP melt in the crucible within a tight inner chamber having an independently heated reservoir of condensed phase phosphorus to maintain a controlled phosphorus pressure and with optimized graphite heaters around the chamber.
Bridgman is a boat growth method by solifying the InP melt from a seed crystal placed at a bottom seeded crucible with a set of graphite resistance heaters regulated separately to guarantee the solidification sliding the thermal profile along the crucible.
In both cases the growth assembly and the heater system are enclosed in a water-cooled high pressure stainless steel vessel, boron oxide acts as an encapsulant suppressing phosphorus evaporation, the power is controllably ramped down until the entire charge is solidified with the surrounding insulation designed to produce a smooth thermal profile.
The InP single crystal is doped at this stage by introducing impurities in the bath such as iron, sulphur, tin or zinc.
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